Polyoxometalates for the Catalytic Reduction of Nitrogen Oxide and Derivatives: From Novel Structures to Functional Applications

Nitrogen oxide and its derivatives, including nitroaromatic hydrocarbons and various other nitro compounds, are commonly used in industrial applications such as synthesizing drugs, dyes, pesticides, and explosives. However, these compounds are also highly toxic to the environment. Their long-term accumulation can significantly affect air and water quality and disrupt ecosystems. Thus, efficiently converting these harmful compounds into more valuable products through catalytic processes is an urgent challenge in chemical catalysis. In this regard, polyoxometalates (POMs) have emerged as promising inorganic molecular catalysts for the reduction of nitrogen oxide and its derivatives. Their unique structure, excellent redox properties, and versatile catalytic abilities contribute to their effectiveness. This review provides an overview of recent advancements in the POM-catalyzed reduction of nitrogen oxide and its derivatives, focusing on reducing nitroaromatic hydrocarbons and nitrogen oxides. Additionally, we discuss the reaction mechanisms involved in the catalytic process, explore the potential of POMs' structural features for the rational design and optimization of catalytic performance, and highlight future directions for developing POM-based catalysts.