茂金属
三联烯
烯烃聚合
聚合
烯烃纤维
催化作用
高分子化学
材料科学
化学
有机化学
聚合物
作者
Pavel S. Kulyabin,Mikhail I. Sharikov,Vyatcheslav V. Izmer,Dmitry S. Kononovich,Georgy P. Goryunov,Nikita V. Alexeev,Dmitry V. Uborsky,Antonio Vittoria,Giuseppe Antinucci,Christian Ehm,Peter H. M. Budzelaar,Roberta Cipullo,Vincenzo Busico,Alexander Z. Voskoboynikov
摘要
A set of metallocene catalysts bearing triptycene moieties in different positions was tested in olefin (co)polymerization. Comparison of results with QSPR predictions not parametrized for these exotic ligand variations demonstrates that trends can still be identified by extrapolation.
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