An Anti‐Fracture and Super Deformable Soft Hydrogel Network Insensitive to Extremely Harsh Environments

Design of hydrogels with superior flexible deformability, anti-fracture toughness, and reliable environment adaption is fundamentally and practically important for diverse hydrogel-based flexible devices. However, these features can hardly be compatible even in elaborately designed hydrogels. Herein soft hydrogel networks with superior anti-fracture and deformability are proposed, which show good adaption to extremely harsh saline or alkaline environments. The hydrogel network is one-step constructed via hydrophobic homogenous cross-linking of poly (sodium acrylate), which is expected to provide hydrophobic associations and homogeneous cross-linking for energy dissipation. The obtained hydrogels are quite soft and deformable (tensile modulus: ≈20 kPa, stretchability: 3700%), but show excellent anti-fracture toughness (10.6 kJ m-2 ). The energy dissipation mechanism can be further intensified under saline or alkaline environments. The mechanical performance of the hydrophobic cross-linking topology is inspired rather than weakened by extremely saline or alkaline environments (stretchability: 3900% and 5100%, toughness: 16.1 and 17.1 kJ m-2 under saturated NaCl and 6 mol L-1 NaOH environments, respectively). The hydrogel network also shows good performance in reversible deformations, ion conductivity, sensing strain, monitoring human motions, and freezing resistance under high-saline environments. The hydrogel network show unique mechanical performance and robust environment adaption, which is quite promising for diverse applications.