热解
超级电容器
碳纤维
材料科学
化学工程
假电容
杂原子
多孔性
比表面积
功率密度
电容
化学
复合材料
有机化学
复合数
量子力学
物理
工程类
物理化学
催化作用
功率(物理)
电极
戒指(化学)
作者
Xikui Zhang,Xiaoqian Ma,Zhaosheng Yu,Yanjie Yi,Changxing Lu,Xiaoluan Lu
标识
DOI:10.1016/j.jaap.2023.106061
摘要
Biomass carbon, particularly heteroatom-doped porous carbon with additional pseudocapacitance, is widely used as an energy storage material. In this study, N-self-doped porous carbon enriched with hierarchical pore structures was prepared via microwave-assisted pyrolysis of water hyacinth. The porous carbon obtained at a heating power of 500 W and a final temperature of 700 °C (WPC-T7P5) has the highest specific surface area (SSA) of 2649 m2/g. In addition, WPC-T7P5 has abundant nitrogen-containing functional groups and a total N content of 2.73%. The carbon morphology and thermal stability show that the inorganic carbon content of WPC-T7P5 reaches 39.87% with a stable carbon structure. WPC-T7P5 possesses a specific capacitance of 374 F/g at 0.2 A/g and 254 F/g at 20 A/g, respectively, with a capacitance retention of 67.91%. A symmetrical supercapacitor based on WPC-T7P5 exhibits a maximum energy density of 8.09 Wh/kg at a power density of 50 W/kg. This study presents a novel microwave-assisted green technique to fabricate N-self-doped porous carbon.
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