催化作用
介质阻挡放电
氧化物
等离子体
非热等离子体
分解
同轴
金属
化学
吸附
化学工程
填充床
分析化学(期刊)
无机化学
材料科学
物理化学
电极
色谱法
有机化学
物理
工程类
量子力学
电气工程
作者
M. Umamaheswara Rao,K. Bhargavi,Giridhar Madras,Ch. Subrahmanyam
标识
DOI:10.1016/j.cej.2023.143671
摘要
A coaxial dielectric barrier discharge (DBD) reactor was used to perform catalytic non-thermal plasma for CO2 conversion under ambient conditions. A systematic study was made to understand the role of basic oxides in activating weakly acidic CO2. For this purpose, MO/γ-Al2O3 (M = Mg, Ca, Sr, and Ba) catalysts were synthesized and integrated with the DBD reactor. The applied voltage was varied from 16 kV to 22 kV to determine the effect of applied voltage on CO2 conversion. Plasma discharge generates high-energy electrons that activate the basic oxides. Integration of basic metal oxides with the non-thermal plasma reactor resulted in a higher CO2 conversion. The adsorption of weakly acidic CO2 on the basic sites is responsible for the higher conversion of catalytic plasma reactor over plasma reactor alone. Among the basic metal oxides studied, SrO loaded γ-Al2O3 resulted in the best conversion, where CO2 conversion of ∼ 12% and energy efficiency of ∼ 1.46 mmol kJ−1 was attained at a power of 1.8 W. The concentration of O2 and O3 was measured during the reaction. The hybridized system's superior performance may be due to increased charge deposition and altered gas-phase chemistry because of catalyst integration. BOLSIG + software was used to compute the mean electron energies and electron energy distribution function for various packing conditions.
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