甲醇
二氧化碳
可再生能源
碳纤维
催化作用
温室气体
放热反应
化学
氢
化学工程
材料科学
有机化学
复合材料
工程类
电气工程
复合数
生物
生态学
作者
Shaoqu Xie,Wanli Zhang,Xingying Lan,Hongfei Lin
出处
期刊:Chemsuschem
[Wiley]
日期:2020-11-11
卷期号:13 (23): 6141-6159
被引量:59
标识
DOI:10.1002/cssc.202002087
摘要
Abstract Excessive carbon dioxide (CO 2 ) emissions have been subject to extensive attention globally, since an enhanced greenhouse effect (global warming) owing to a high CO 2 concentration in the atmosphere could lead to severe climate change. The use of solar energy and other renewable energy to produce low‐cost hydrogen, which is used to reduce CO 2 to produce bulk chemicals such as methanol, is a sustainable strategy for reducing carbon dioxide emissions and carbon resources. CO 2 conversion into methanol is exothermic, so that low temperature and high pressure are favorable for methanol formation. CO 2 is usually captured and recovered in the liquid phase. Herein, the emerging technologies for the hydrogenation of CO 2 to methanol in the condensed phase are reviewed. The development of homogeneous and heterogeneous catalysts for this important hydrogenation reaction is summarized. Finally, mechanistic insight on CO 2 ’s conversion into methanol over different catalysts is discussed by taking the available reaction pathways into account.
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