脱氢
钴
甲酸
光化学
制氢
氢
光催化
化学
催化作用
催化循环
二氧化碳
无机化学
有机化学
作者
Takuya Akai,Mio Kondo,Yoshitaka Saga,Shigeyuki Masaoka
摘要
The first catalytic cycle for hydrogen production based on the photochemical two-electron reduction of carbon dioxide (CO2) and the dehydrogenation of formic acid at ambient temperature was demonstrated using a pentanuclear cobalt complex (Co5). A series of mechanistic studies were performed to elucidate the mechanism responsible for the promotion of the photocatalytic cycle by Co5.
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