塔菲尔方程
过电位
双功能
电催化剂
分解水
析氧
材料科学
阳极
催化作用
化学工程
纳米技术
电化学
化学
电极
物理化学
工程类
有机化学
光催化
作者
Zexing Wu,Dazong Nie,Min Young Song,Tiantian Jiao,Gengtao Fu,Xien Liu
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2019-01-01
卷期号:11 (15): 7506-7512
被引量:192
摘要
Design of cost-effective bifunctional electrocatalysts for both the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is vital for developing hydrogen energy for the future. Herein, a cost-effective phosphorus-doped Co-Fe-B material with chain-like structure (denoted as Co1-Fe1-B-P) is reported as an efficient and novel bifunctional electrocatalyst for the OER and HER, and was produced via a facile water-bath synthesis and subsequent phosphorization. For the OER, the as-prepared Co1-Fe1-B-P nanochains require an extremely low overpotential of about 225 mV at 10 mA cm-2 and possess a small Tafel slope of 40 mV dec-1 in alkaline media. Impressively, the HER properties of Co1-Fe1-B-P nanochains are superior to those of P-free Co-Fe-B in terms of overpotential at 10 mA cm-2 (173 mV vs. 239 mV) and kinetic Tafel slope (96 mV dec-1vs. 105 mV dec-1). The synergetic effect between Co-Fe-B and doped-P is mainly responsible for the satisfactory bifunctional performance, while the one-dimensional (1D) chain-like structure endows Co1-Fe1-B-P with abundant catalytically active sites that enhance the atom utilization efficiency. Moreover, the developed Co1-Fe1-B-P nanochains can be simultaneously utilized as both the cathode and anode for overall water-splitting, which requires a cell voltage of only 1.68 V to deliver 10 mA cm-2. This work provides a feasible and promising protocol to realize metal borides as efficient electrocatalysts in energy-related applications.
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