催化作用
同种类的
金属有机骨架
纳米技术
多样性(控制论)
材料科学
液相
金属
相(物质)
班级(哲学)
化学
计算机科学
有机化学
物理
冶金
人工智能
吸附
热力学
作者
Frederik Vermoortele,Pieterjan Valvekens,Dirk De Vos
出处
期刊:The Royal Society of Chemistry eBooks
[The Royal Society of Chemistry]
日期:2013-07-08
卷期号:: 268-288
被引量:7
标识
DOI:10.1039/9781849737586-00268
摘要
The intrinsically high metal content of MOFs makes them appealing for use in catalysis. Over the past few years, a wide variety of MOFs has been intensively studied as catalysts in various liquid phase organic reactions. The most intriguing class of MOF catalysts is that in which the structural nodes themselves act as the catalytic centres. This chapter will give an overview of some research on MOF catalysts in which the metal ions are the active sites. The examples given show that this class of materials offers a unique opportunity to finely tune the active site with tools previously only available in homogeneous complexes. This aspect, combined with their facile recycling, raises high expectations that MOFs can be applied by industry in the near future.
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