The test is studied the alcoholysis of 1,2-eporypropane with ZrO_2/SO_4 solid super-acid as catalyst.Confirm the best reaction conditions and compare the catalytic activity of ZrO_2/SO_4 solid super-acid with heteropoly blue.ZrO_2/SO_4 solid super-acid is a good catalyst for Alcoholysis of 1,2-Eporypropane.