双功能
电催化剂
石墨烯
材料科学
析氧
催化作用
化学工程
钴
氧化物
纳米复合材料
电解
电化学
制作
纳米技术
硫化钴
无机化学
化学
电极
冶金
有机化学
物理化学
替代医学
病理
电解质
工程类
医学
作者
Yuqi Xu,Yongchao Hao,Guoxin Zhang,Xiuyan Jin,Lin Wang,Zhiyi Lu,Xiaoming Sun
标识
DOI:10.1002/ppsc.201500242
摘要
Herein, a strategy for one‐step fabrication of cobalt sulfide/graphene (Co 1− x S/G) nanocomposite as bifunctional catalyst for oxygen catalysis is demonstrated. The one‐step fabrication method involves annealing the mixture of cobalt salt, thioacetamide, and graphene oxide with the assistance of small amount of glycol without any further purification steps. The Co 1− x S/G shows a morphology with small‐sized Co 1− x S nanocrystals strongly and uniformly anchored on the graphene surface. Systematically electrochemical studies demonstrate that the Co 1− x S/G with optimized components shows superior catalytic activities toward oxygen reduction and oxygen evolution, which are comparable or even superior to commercial Pt/C and Ir/C catalysts. As a result, the potential hysteresis of Co 1− x S/G is the lowest among all the samples. The facile operability of the fabrication method and the high bifunctional activity of Co 1− x S/G may pave one practical way for broad applications including fuel cell, metal‐O 2 battery, and water electrolysis.
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