Environment-friendly dual-network hydrogel dust suppressant based on xanthan gum, polyvinyl alcohol and acrylic acid

黄原胶 丙烯酸 乙烯醇 化学工程 聚乙烯醇 聚丙烯酸 煤尘 自愈水凝胶 材料科学 丙烯酸树脂 表面张力 抗压强度 复合材料 化学 聚合物 高分子化学 涂层 有机化学 流变学 物理 单体 量子力学 工程类
作者
Jianfeng Wei,Yanyun Zhao,Shijian Yu,Jianhua Du,Xiangming Hu,Guangxing Bai,Zhaoxi Wang
出处
期刊:Journal of Environmental Management [Elsevier BV]
卷期号:295: 113139-113139 被引量:45
标识
DOI:10.1016/j.jenvman.2021.113139
摘要

Hydrogen bonding interactions among poly vinyl alcohol (PVA), xanthan gum (XG) and acrylic acid (AA) molecules have been utilized to prepare an environment-friendly interpenetrating double-network hydrogel dust suppressant (PVA-XG-PAA/SDBS) with the aim of enhancing the poor mechanical performance of current hydrogel dust suppressants. A single factor test was used to determine the optimal formulation conditions for the PVA-XG-PAA/SDBS, and the viscosity, surface tension, compression strength, wind resistance, water retention and biodegradability of the samples were measured. The results showed that the hydrogel with optimal usage contained 1.5 g, 0.1 g, and 6 g of PVA, XG and AA, respectively and the optimal reaction temperature was 55 °C. Under the optimal conditions, the viscosity was 45 mPa s, the surface tension was 30 mN/m, the compression strength of the dust suppressant-solidified coal pillar reached 126 kPa, and the degradation rate at the 8th cycle (40 days) after being buried in soil was 34%. Compared with a conventional hydrogel dust suppressant, like poly acrylic acid (PAA), and the dust suppressant sodium dodecyl benzene sulfonate (SDBS), the PVA-XG-PAA/SDBS showed better water retention, wind erosion resistance, and dust-solidifying properties. On the basis of these remarkable properties, the PVA-XG-PAA/SDBS is applicable for dust prevention during coal mining, transport, and storage, which enhances the dust suppression efficiency obviously and has significant meaning to the sustainable development of the coal mining industry while protecting the environment.
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