阳极
碳化
钾
纳米孔
多孔性
碳纤维
材料科学
离子
扩散
化学工程
纳米技术
化学
复合材料
冶金
电极
有机化学
扫描电子显微镜
热力学
工程类
物理化学
复合数
物理
作者
S. J. Richard Prabakar,Su Cheol Han,Chunguk Park,Amol Bhairuba Ikhe,Michael J. Reece,Kee‐Sun Sohn,Myoungho Pyo
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2017-01-01
卷期号:164 (9): A2012-A2016
被引量:44
摘要
For the first time we report that hard-wood (oak) can spontaneously create interconnected channels of μm to nm in diameter during carbonization at an optimized temperature (1100°C). These microstructural features have never been found in other hard-carbons without the use of additives. When compared with sucrose-based hard-carbon (SHC), oak-based hard-carbon (OHC) shows much higher charge-storage capability (ca. 223 vs. 112 mAh·g−1 at 20 mA·g−1) and excellent stability (fading rate of 0.04 vs. 0.08%·cycle−1) as an anode in potassium-ion batteries. The high performance of OHC mainly results from interwoven nanoporous channels, which lead to facile charge transfer and fast K+-diffusion.
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