六价铬
聚苯胺
聚吡咯
吸附
生物炭
吸附
聚合
化学
苯胺
核化学
比表面积
铬
弗伦德利希方程
热解
无机化学
有机化学
聚合物
催化作用
作者
Wei Mao,Ying Zhang,Jinen Luo,Lingtiao Chen,Yuntao Guan
出处
期刊:Chemosphere
[Elsevier]
日期:2022-09-01
卷期号:303: 135254-135254
被引量:17
标识
DOI:10.1016/j.chemosphere.2022.135254
摘要
It is still a huge challenge to prepare cheap and effective composite materials for removing hexavalent chromium (Cr(VI)) in sewage treatment. In this study, a noval co-polymerization of polypyrrole/polyaniline on ferrate modified biochar (Ppy/PANI/FBC) was fabricated via ferrate-promoted pyrolysis and in-situ oxidative polymerization of pyrrole and aniline molecules to effectively remove Cr(VI) from polluted water. The Ppy/PANI/FBC quickly decreased Cr(VI) concentration from 38.92 to 3.92 mg/L within 400 min, with an efficient removal efficiency (89.92%), which was significantly higher than that of FBC (4.75%), Ppy/FBC (72.30%), and PANI/FBC (42.43%). These results are mainly caused by its conjugated connection and well-dispersion of Ppy and PANI on the surface of a carbon-based material. Meanwhile, the experimental results were in line with the pseudo-second-order kinetic and Freundlich models. The Ppy/PANI/FBC is featured by a high capacity of Cr(VI) adsorption (up to 203.71 mg/g). In addition, it could be adopted for efficiently removing Cr(VI) over a wide pH range (4-9) because of the positively charged nitrogen (-NH.+- and = N+-). The sorption mechanisms of Cr(VI) were identified, including electrostatic interaction with surface protonated nitrogen (N+), ion exchange between the doped Cl- ions and Cr(VI), chemical decrease of the Cr(VI) to Cr(III) by the iron valence cycle and efficient electron transfer of Ppy/PANI/FBC, as well as surface complexation by amine and oxygen-containing groups. More importantly, 97.98% Cr(VI) was efficiently removed in 20 min by coupling a photocatalytic reaction, also providing a novel idea for the practical use of adsorbents in wastewater treatment.
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