Effect of aluminum hydroxide (ATH) on flame retardancy and smoke suppression properties of SBS-modified asphalt

极限氧指数 材料科学 沥青 阻燃剂 烟雾 复合材料 傅里叶变换红外光谱 扫描电子显微镜 炭黑 吸附 热解 化学工程 有机化学 化学 烧焦 天然橡胶 工程类
作者
Xiaolong Yang,Guangchen Wang,Mingmei Liang,Taiping Yuan,Hongliu Rong
出处
期刊:Road Materials and Pavement Design [Taylor & Francis]
卷期号:24 (1): 173-190 被引量:27
标识
DOI:10.1080/14680629.2021.2012239
摘要

In this study, ATH-modified asphalt of different compositions (0wt%, 5wt%, 10wt%, 15wt%, and 20wt%) were prepared for testing. Its flame-retardant performance and dynamic smoke release characteristics were investigated by using the limiting oxygen index (LOI) test and TG-FTIR technology. After pyrolysis, the carbon layer's structure, morphology, and element distribution were analyzed by scanning electron microscopy-energy disperse spectroscopy (SEM-EDS). Adding ATH increased the LOI value of the base asphalt by up to 23.1%. The TG-FTIR results showed that ATH significantly improved the flame-retardant performance of asphalt through three physical effects: cooling, dilution, and heat insulation. Adding ATH to asphalt affected adsorption and blocking, thus reducing smoke, promoting carbon formation, and improving its smoke suppression. Observations of the microscopic carbon layer showed that incorporating ATH improved the integrity and strength of its structure. Based on these results, a mechanistic model of the flame retardancy and smoke suppression of ATH-modified asphalt was established.
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