阳极
材料科学
锂(药物)
碱金属
化学工程
电化学
X射线光电子能谱
储能
氧化物
电极
化学
冶金
有机化学
医学
功率(物理)
物理
物理化学
量子力学
工程类
内分泌学
作者
Jing Li,Hui Wei,Feng Hu,Zhong Xie,Jinpei Hei,Yaqiong Kong,Xiaojie Yin,Nannan Wang,Hehe Wei
标识
DOI:10.1016/j.ijhydene.2022.07.145
摘要
MoO2 anode displays excellent potential in the alkali ion batteries owing to its large capacity, high conductivity and stability. However, exploiting the stable and high performance MoO2 anode endowed with triple roles for the storage of lithium/sodium/potassium ions is still a challenge. Herein, a two-dimensional sheet-like MoO2/NPC@rGO composites were in-situ synthesized and utilized as anode materials for alkali metal ion batteries. Applied as an anode in lithium ion batteries (LIBs), superior cycling capability and rate performance were obtained, which kept a large reversible capacity of 1233.1 mAh/g in the 200th cycle at 100 mA/g. Impressively, it displayed superior long cycling performance over 1000 cycles with a 249.5 mAh/g capacity at a high current density of 10 A/g. Simultaneously, MoO2/NPC@rGO displayed enhanced electrochemical performance both in sodium and potassium ion batteries (NIBs/KIBs). Furthermore, the ex-situ X-ray photoelectron spectroscopy results verified the reversible reaction during Li+ insertion-extraction process. The improved energy storage properties were attributed to the typical two dimensional structure and synergistic effects between various constituents, which suppressed the volume change, created more active sites, increased the conductivity and facilitated reaction kinetics. More significantly, our design provides a simple and green route to synthesize transition metal oxide anode and promote their applications in energy storage devices.
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