制作
材料科学
涂层
钙钛矿(结构)
可控性
纳米技术
再现性
化学工程
化学
医学
替代医学
数学
病理
色谱法
应用数学
工程类
作者
Jingjing Liang,Daxue Du,Chao Gao,Feiyang Qiao,Li He,Dezhao Zhang,Jiahao Bao,Hong Liang,Wei Shen
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2023-10-19
卷期号:6 (21): 10842-10852
被引量:1
标识
DOI:10.1021/acsaem.3c01495
摘要
Organic–inorganic hybrid perovskite solar cells (PSCs) have exhibited great progress in recent years, although it still remains challenging to translate them from the lab to the fab for commercialization. Further process simplification and design of stable ink formulations are required to ensure fine control over the perovskite film quality for scalable coating. In this work, a facile and controllable room-temperature fabrication of high-performance bladed PSCs in air is proposed by directly introducing the green solvent methylammonium acetate (MAAc) into low-toxicity 2-methoxyethanol (2-Me). This combination could better control the formation process of perovskite by forming the perovskite-like intermediate phase with PbI2 in its unique ionic network so as to facilitate the film uniformity and the process reproducibility; meanwhile, the high volatility of 2-Me still enables the low-temperature fabrication. Consequently, with the assistance of a benzohydrazide (BZH) passivator, the target device achieves a champion PCE of 20.11% and a superior fill factor of 82.8% in inverted MAPbI3-based devices, along with significant device stability. Herein, the strategy provides a feasible prospect for scalable coating to fabricating high-performance PSCs with high reproducibility and controllability under ambient conditions.
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