超级电容器
材料科学
电极
电容
功率密度
结晶度
电化学
化学工程
离子
纳米技术
分析化学(期刊)
复合材料
化学
功率(物理)
色谱法
物理化学
有机化学
热力学
物理
工程类
作者
Lingfeng Wang,Lu Chen,Shihuan Chen,Qinglan Ye,Xuetang Xu,Fan Wang
标识
DOI:10.1002/chem.202203898
摘要
Anion exchange is recognized as an effective method to regulate the composition, electronic conductivity, and electrochemical behavior of the transition metal-based compounds. In this work, anion exchange is adopted as a rational post-treatment route to facilitate the capacitive activity of CoNi2 S4 nanoparticle arrays grown on carbon cloth (CC) with high mass-loading. As soaked in saturated Na2 S solution, the CoNi2 S4 /CC electrode showed an increased capacity from 483 C g-1 to 841 C g-1 at 10 mA cm-2 with excellent rate performance and stable cycling performance, which was superior to the CoNi2 S4 /CC electrode activated by NaBH4 reduction. Anion exchange was beneficial for enhancing the crystallinity, retaining the adhesion of nanoarrays, and realizing low resistance nature in a mild route. The as-assembled CoNi2 S4 /CC//activated CC hybrid supercapacitor delivered a high areal capacitance of 1.28 F cm-2 at 5 mA cm-2 , and achieved an energy density of 0.58 mWh cm-2 at a power density of 4.5 mW cm-2 with excellent cycle stability with 90.6 % capacity retention after 10000 cycles.
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