Recent Advances in Natural Products Synthesis Using Bifunctional Organocatalysts Bearing a Hydrogen‐Bonding Donor Moiety

Abstract Organocatalysis is widely used for the asymmetric synthesis of natural products and pharmaceuticals, and bifunctional organocatalysts are particularly effective for controlling stereochemistry. Here, we present an overview of natural products syntheses involving bifunctional catalysts bearing a hydrogen‐bonding donor moiety reported during the last five years.