钝化
碘化物
钙钛矿(结构)
卤化物
材料科学
光伏系统
能量转换效率
卤素
分子间力
图层(电子)
化学工程
太阳能电池
纳米技术
光电子学
化学
结晶学
无机化学
分子
有机化学
烷基
电气工程
工程类
作者
Sanghyun Paek,Cristina Roldán‐Carmona,Kyung Taek Cho,Marius Franckevičius,Hobeom Kim,Hiroyuke Kanda,Nikita Drigo,Kun‐Han Lin,Mingyuan Pei,Rokas Gegevičius,Han Young Woo,Hoichang Yang,Pascal Schouwink,Clémence Corminbœuf,Abdullah M. Asiri,Mohammad Khaja Nazeeruddin
标识
DOI:10.1002/advs.202001014
摘要
Abstract Despite organic/inorganic lead halide perovskite solar cells becoming one of the most promising next‐generation photovoltaic materials, instability under heat and light soaking remains unsolved. In this work, a highly hydrophobic cation, perfluorobenzylammonium iodide (5FBzAI), is designed and a 2D perovskite with reinforced intermolecular interactions is engineered, providing improved passivation at the interface that reduces charge recombination and enhances cell stability compared with benchmark 2D systems. Motivated by the strong halogen bond interaction, (5FBzAI) 2 PbI 4 used as a capping layer aligns in in‐plane crystal orientation, inducing a reproducible increase of ≈60 mV in the V oc , a twofold improvement compared with its analogous monofluorinated phenylethylammonium iodide (PEAI) recently reported. This endows the system with high power conversion efficiency of 21.65% and extended operational stability after 1100 h of continuous illumination, outlining directions for future work.
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