氟化物
色谱法
化学
离子色谱法
尿
检出限
洗脱
氢氧化物
离子
氢氧化钾
作者
F G Zhang,H F Yan,Y J Pan,W Zhao
出处
期刊:Chinese Journal of Industrial Hygiene and Occupational Diseases
[zhong hua yi xue hui]
日期:2017-08-20
卷期号:35 (8): 622-624
标识
DOI:10.3760/cma.j.issn.1001-9391.2017.08.019
摘要
Objective: To establish a method to determine fluorine ion in human urine by ion chromatography method. Methods: The samples were centrifuged, diluted and processed by C(18) solid-phase column, potassium hydroxide as mobile phase, gradient elution, separated by AS(15), and determined by anion conductivity detector. Results: The linear correlation coefficient of fluoride ion in the range of 0.02-10.00 mg/L was more than 0.999. The lowest detection limit of urinary fluoride was 0.06 mg/L (in 3 ml urine) . The recoveries of the method were 96.9%-99.5%, the inter batch precision range was 0.40%-2.89%. The intra batch precision was from 1.01 to 7.23%. Fluoride samples could be stored for 7 days at room temperature and 4 ℃, and be stored for 14 days at -20 ℃. Conclusion: Determination of fluoride in urine by ion chromatography, the method could meet the requirement in GBZ/T 210.5-2008.
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