杂原子
微型多孔材料
超级电容器
三元运算
重量分析
材料科学
比表面积
热解
电极
化学工程
碳纤维
多孔性
电解质
活性炭
电化学
吸附
纳米技术
复合材料
化学
复合数
催化作用
计算机科学
有机化学
戒指(化学)
程序设计语言
物理化学
工程类
作者
Jin Niu,Mengyue Liu,Feng Xu,Zhengping Zhang,Meiling Dou,Feng Wang
出处
期刊:Carbon
[Elsevier]
日期:2018-12-01
卷期号:140: 664-672
被引量:95
标识
DOI:10.1016/j.carbon.2018.08.036
摘要
Porous carbon materials are the most widely used electrode materials in supercapacitors. Numerous works focus on increasing specific surface area and engineering hierarchical porosity as well as doping heteroatoms to improve the gravimetric performance for porous carbon electrodes. However, highly porous structures will cause low density for porous carbon electrodes, resulting in poor volumetric performance. The complex synthesis methods also restrict the wide applications of the resultant carbons. In this work, we demonstrate a sustainable and efficient strategy to synthesize ternary-doped microporous carbon nanosheets via treating fish skin with KOH. Notably, KOH firstly turns the fish skin into water-soluble gelatin, then KOH-derived potassium compounds simultaneously act as templates and activators to form micropore-dominant carbon nanosheets. The precursor (fish skin) and reagent (KOH) are low-cost, and potassium compound in the resultant carbons (K2CO3) is low-toxicity and easy-disposal. The relatively low pyrolysis temperature (600 °C) reserves numerous O, N and S heteroatoms derived from fish skin and leads to rational specific surface area, pore volume and compacting density of the porous carbon nanosheets. Beneficial from the unique nanostructure and rich surface heteroatoms, the resultant carbon shows integrated high gravimetric and volumetric performance as electrode for supercapacitor in aqueous electrolyte.
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