层流
电解质
阳极
甲醇
电化学
材料科学
阴极
碱性燃料电池
电化学动力学
无机化学
动力学
化学工程
化学
电极
热力学
有机化学
物理化学
工程类
物理
量子力学
作者
Ranga S. Jayashree,Daniela Egas,Jacob S. Spendelow,Dilip Natarajan,Larry J. Markoski,Paul J. A. Kenis
摘要
We report the performance of an air-breathing laminar flow-based fuel cell (LFFC) operated in alkaline and acidic media. These direct methanol fuel cells exhibit open-circuit potentials of 0.93 and in acidic and alkaline media, respectively, demonstrating the absence of methanol crossover in both media. The LFFCs perform better in alkaline media under identical reaction conditions due to improved reaction kinetics at high pH. Further electrochemical investigation of these differences in reaction kinetics at the anode and cathode is also reported.
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