Boosting the Productivity of Electrochemical CO2Reduction to Multi‐Carbon Products by Enhancing CO2Diffusion through a Porous Organic Cage

Abstract Electroreduction of CO 2 into valuable fuels and feedstocks offers a promising way for CO 2 utilization. However, the commercialization is limited by the low productivity. Here, we report a strategy to enhance the productivity of CO 2 electroreduction by improving diffusion of CO 2 to the surface of catalysts using porous organic cages (POCs) as an additive. It was noted that the Faradaic efficiency (FE) of C2+ products could reach 76.1 % with a current density of 1.7 A cm −2 when Cu‐nanorod(nr)/CC3 (one of the POCs) was used, which were much higher than that using Cu‐nr. Detailed studies demonstrated that the hydrophobic pores of CC3 can adsorb a large amount of CO 2 for the reaction, and the diffusion of CO 2 in the CC3 to the nanocatalyst surface is easier than that in the liquid electrolyte. Thus, more CO 2 molecules make contact with the nanocatalysts in the presence of CC3, enhancing CO 2 reduction and inhibiting generation of H 2 .