腐蚀
钝化
材料科学
无定形固体
合金
冶金
硫酸
降水
电流密度
非晶态金属
化学工程
无机化学
复合材料
化学
图层(电子)
有机化学
工程类
物理
量子力学
气象学
作者
Xiaodong Yang,Meng Gao,Qing Liu,Jinlong Li,Yan Huang,Gang Wang,Junqiang Wang,Juntao Huo
标识
DOI:10.1016/j.corsci.2022.110227
摘要
In this work, the corrosion behaviors and underlying mechanisms of high-temperature Ir-based amorphous alloys in an acidic solution were investigated systematically. The Ir-Ni-Ta-B amorphous alloy exhibits a crevice corrosion behavior with a superior corrosion resistance characterized by a low passive current density and a wide passive potential range. It is found that the high-exchange current density of H+ and H2 couple on the metalloid constituent can accelerate the active precipitation of passivation elements, leading to rapid formation of passive film. In sulfuric acid solutions, the formed passive film containing Ir, Ta5+ and Ni3+ oxides significantly increase the corrosion resistance.
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