In the present thesis, we report several general properties of the enhancement of the entanglement by external fields. First, we investigate the thermal entanglement of interacting two qubits. We maximize it by tuning a local Hamiltonian under a given interaction Hamiltonian. We prove that the optimizing local Hamiltonian takes a simple form which dose not depend on the temperature and that the corresponding optimized thermal entanglement decays as 1/(T log T ) at high temperatures. We also find that at low temperatures the thermal entanglement is maximum without any local Hamiltonians and that the second derivative of the maximized thermal entanglement changes discontinuously at the boundary between the highand low-temperature phases. Second, we investigate the maximized entanglement of indirectly interacting two spins, that is, through other spins. We present a necessary condition for the indirect interaction to give a non-zero maximized entanglement between the focused spins. We also prove that if the focused spins are separated by two spins, there is a critical temperature above which the maximized entanglement between the focused spins vanishes. Then, we numerically calculate the maximized entanglement between the end spins of three-spin chains and four-spin chains. We discover that the maximizing local fields on the end spins have asymmetric forms. In the three-spin chains, we attribute the entanglement enhancement to the asymmetry of the local fields qualitatively and quantitatively in terms of the magnons. In XX and XY four-spin chains, we find that the critical temperature shows qualitatively different behavior depending on the conservation of the angular momentum in the z direction.