甲基橙
光催化
X射线光电子能谱
光降解
高分辨率透射电子显微镜
可见光谱
材料科学
热液循环
肖特基势垒
纳米颗粒
光电子学
光化学
化学工程
纳米技术
化学
透射电子显微镜
催化作用
有机化学
二极管
工程类
作者
Lixiong Yin,Haofan Zhang,Jianfeng Huang,Xingang Kong,Huimin Li,Peijie Bai,Jiaqi Song
标识
DOI:10.1007/s10854-019-02730-x
摘要
In this work, a highly photocatalytic Ag/In2S3 was synthesized via the hydrothermal and photoreduction method. The as-prepared photocatalysts were confirmed by XRD, SEM, HRTEM, and XPS showing that Ag nanoparticles were decorated on the In2S3 surface. Photocatalytic activities of photocatalysts were investigated for photodegradation of methyl orange (MO) under visible light. The Ag/In2S3 composites showed the enhanced photocatalytic efficiency of 97% under visible light irradiation for 90 min, which was about 3.0 times higher than that of pure In2S3. The enhanced photocatalytic performance could be owing to the SPR of Ag and the Schottky junction formed between Ag and In2S3. Our PL results indicate the inhibited recombination of the photogenerated electron–hole pairs in In2S3 upon the attachment of Ag nanoparticles. The active species tests demonstrate that the superoxide radical (·O2−) and h+ are responsible for the efficient degradation of MO over Ag/In2S3. In addition, it also proposes a potential mechanism for enhancing the photocatalytic activity.
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