水溶液
化学
焓
动力学
解吸
氨基酸
动能
色谱法
反应速率常数
热力学
物理化学
吸附
生物化学
物理
量子力学
作者
Yi-Feng Chen,Biao Li,Jian Wu,Zhuhong Yang,Xiaohua Lu,Xiaoyan Ji
标识
DOI:10.1016/j.seppur.2020.118284
摘要
The thermodynamic and kinetic properties of CO2 in aqueous choline-amino acids ([Cho][AA]s) are important information to demonstrate their performance. In this study, the apparent kinetic properties of CO2 in the five aqueous [Cho][AA]s, including the liquid-side mass-transfer coefficients, enhancement factor, and reaction rate constant, were systematically studied. Furthermore, a new ‘‘absorption ability’’ (AA) index was proposed, combining the apparent kinetic properties determined in this study and thermodynamic properties determined in our previous study. The CO2 separation performance using aqueous [Cho][AA]s was evaluated based on the AA and CO2 desorption enthalpy values. The results show that 30 wt% aqueous choline-serine is a promising absorbent for CO2 separation, and it is comparable to aqueous monoethanolamine.
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