破乳剂
吸附
化学工程
肺表面活性物质
单层
化学
材料科学
色谱法
有机化学
乳状液
纳米技术
工程类
作者
Mian Wu,Mengjin Zhai,Xiao Bing Li
标识
DOI:10.1016/j.powtec.2020.09.068
摘要
A novel [email protected] demulsifier was developed through grafting branched polyether polysiloxane (PPS) molecules onto the ZIF-8 crystal. This demulsifier presented a rough surface structure with interconnected pores, large surface area and high hydrophobicity. When processing the simulated alkaline-surfactant-polymer (ASP) flooding produced water that contained 0.4 g L−1 oil, the demulsifier exhibited an oil removal rate of 90.03%, much higher than that of PPS (65.66%) and ZIF-8 (55.43%). The excellent oil removal rate was ascribed to its abilities to destabilize and coalesce the emulsified fine-sized oil droplets, including the demulsification of PPS and the adsorption of ZIF-8. An adsorption kinetics and isotherm study manifested that oil drops uptake onto ZIF-8 exhibited homogeneous and monolayer adsorption. A maximum adsorption capacity of 1753 mg g−1 was achieved due to the electrostatic and hydrophobic interaction between ZIF-8 and oil. The [email protected] demulsifier with unique oil adsorption properties offers great potential for oily wastewater treatment.
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