原子转移自由基聚合
甲基丙烯酸酯
X射线光电子能谱
接触角
聚合物
嫁接
高分子化学
聚合
钛
表面改性
扫描电子显微镜
材料科学
电子转移
共聚物
化学
化学工程
核化学
有机化学
物理化学
复合材料
工程类
作者
Shuangshuang Wang,Jixuan Song,Yuchao Li,Zhao Xiao-ming,Lin Chen,Guang Li,Liping Wang,Zhengfeng Jia,Xinlei Ge
标识
DOI:10.1016/j.reactfunctpolym.2019.04.002
摘要
An environmentally benign and convenient approach to impart titanium (Ti) surfaces with antibacterial functionalities was described in this work. Polydopamine (PDA) was first deposited onto an alkali activated Ti substrates. Then 2-bromoisobutyryl bromide (BIBB) was immobilized on the surface of PDA coated Ti. Finally, the BIBB functionalized Ti initiated the polymerization of N, N-diethylaminoethyl methacrylate (DEAEMA) and N, N-dimethylaminoethyl methacrylate (DMAEMA) to obtain [email protected] brushes by activators regenerated by electron transfer atom transfer radical polymerization (ARGET-ATRP). The prepared PDEAEMA and PDMAEMA brushes on Ti surfaces would be subsequently quaternized by using 1-bromooctane, which would impart the obtained products with quaternary ammonium groups. The surface compositions of the functionalized Ti were characterized by X-ray photoelectron spectroscopy (XPS). The hydrophilic/hydrophobic properties of the functionalized Ti surfaces were determined by static water contact angle measurements, and morphologies were characterized by scanning electron microscope (SEM). Antibacterial abilities of quaternized PDEAEMA and PDMAEMA coated Ti were evaluated by the contact killing test, in which live/dead cell staining method was employed. The results showed that the quaternized polymer decorated Ti exhibited good bactericidal effects against Escherichi coli (E. coli), and its inhibition rate of E. coli were observed to be nearly 90%.
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