In this paper, we investigate the existence and asymptotic behavior of least energy sign-changing solutions for the following Schrödinger-Poisson system
where \begin{document}$ \lambda>0 $\end{document} is a parameter. Under some suitable conditions on \begin{document}$ f $\end{document} and \begin{document}$ V $\end{document}, we get a least energy sign-changing solution \begin{document}$ u_\lambda $\end{document} via variational method and its energy is strictly larger than twice that of least energy solutions. Moreover, the asymptotic behavior of \begin{document}$ u_\lambda $\end{document} as \begin{document}$ \lambda\rightarrow 0^+ $\end{document} is also analyzed.