Comparison of the catalytic activity of mono‐ and multinuclear Ga complexes in the ROCOP of Epoxides and Cyclic Anhydrides

The catalytically active site of tetranuclear Schiff-base complexes L1–32Ga4(t-Bu)8 1–3, which showed high activity and perfect selectivity (>99 %) in the alternating ROCOP of a series of epoxides and anhydrides to polyesters with high Mn and narrow dispersity Đ, was identified.