材料科学
阴极
惰性
电化学
钠
兴奋剂
离子
化学工程
纳米技术
光电子学
电极
物理化学
冶金
有机化学
化学
工程类
作者
Huiqin Huang,Yufan Xia,Youchen Hao,Haosheng Li,Caiyun Wang,Tingting Shi,Xingyu Lu,Muhammad Wakil Shahzad,Ben Bin Xu,Yinzhu Jiang
标识
DOI:10.1002/adfm.202305109
摘要
Abstract Na 2 FePO 4 F, an iron‐based fluorophosphate with facile 2D sodium ion channels, is considered as a promising cathode material for sodium‐ion batteries because of low cost, resource abundance, and nontoxicity. However, its application is considerably restricted by the limited intrinsic electronic conductivity and specific capacity. Herein, a doping strategy represented by Cu 2+ is proposed to boost the electrochemical performance, attributed to the derivation of a new active Na3 site originated from the inert Na1 site and the band gap reduction due to the d‐orbital hybridization. Consequently, the as‐obtained Na 2 Fe 0.95 Cu 0.05 PO 4 F/C composite can deliver an excellent rate capacity of 74 mAh g⁻ 1 at 20 C and a decent specific capacity of 119 mAh g⁻ 1 at 0.1 C, which is superior to the previously reported Na 2 FePO 4 F‐based cathode materials. This study sheds new light on developing high performance fluorophosphates cathode materials via regulating the Na site and electronic structure.
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