Full‐Color “Off–On” Thermochromic Fluorescent Fibers for Customizable Smart Wearable Displays in Personal Health Monitoring

Abstract Responsive thermochromic fiber materials capable of miniaturization and integrating comfortably and compliantly onto the soft and dynamically deforming human body are promising materials for visualized personal health monitoring. However, their development is hindered by monotonous colors, low‐contrast color changes, and poor reversibility. Herein, full‐color “off–on” thermochromic fluorescent fibers are prepared based on self‐crystallinity phase change and Förster resonance energy transfer for long‐term and passive body‐temperature monitoring, especially for various personalized customization purposes. The off–on switching luminescence characteristic is derived from the reversible conversion of the dispersion state and fluorescent emission by fluorophores and quencher molecules, which are embedded in the matrix of a phase‐change material, during the crystallizing/melting processes. The achievement of full‐color fluorescence is attributed to the large modulation range of fluorescence colors according to primary color additive theory. These thermochromic fluorescent fibers exhibit good mechanical properties, fluorescent emission contrast, and reversibility, showing their great potential in flexible smart display devices. Moreover, the response temperature of the thermochromic fibers is controllable by adjusting the phase‐change material, enabling body‐temperature‐triggered luminescence; this property highlights their potential for human body‐temperature monitoring and personalized customization. This work presents a new strategy for designing and exploring flexible sensors with higher comprehensive performances.