Green preparation of magnetic ferroferric oxide-polyvinyl alcohol-alginate coated UiO-67 nanospheres: Characterization, adsorption properties and adsorption mechanism of methylene blue

In this paper, a kind of magnetic ferric oxide/polyvinyl alcohol/calcium alginate/UiO-67 (Fe3O4/PVA/CA/UiO-67) nanospheres with homogeneous surface interconnecting structures was prepared by using macromolecular polymer polyvinyl alcohol and sodium alginate as carriers and zirconium organic skeleton as nanocrystals. The properties of magnetic nanospheres were studied by SEM, FT-IR, TGA, XRD, BET, VSM and Zeta potential. The impression of diverse temperatures, MB concentrations, interaction time, pH, and magnetic aerogel sphere dose on MB removal was studied. The optimum adsorption temperature and pH of magnetic nanospheres for MB were 298 K, and 10, respectively. Langmuir simulated that the maximum removal of MB by magnetic nanospheres at room temperature (298 K) was 1371.8 mg/g. The removal of MB by magnetic nanospheres complied with the pseudo-first-order kinetic model. The isotherm simulation can infer that the Langmuir model was more comply with MB adsorption on magnetic aerogel spheres. Thermodynamic studies have confirmed that the removal of MB by magnetic nanospheres was exothermic and spontaneous. The interaction mechanism of MB on magnetic nanospheres can be deduced by FT-IR and BET, including hydrogen bond, π-π bond, electrostatic interaction, and mesoporous pore flow. The removal rate of nanospheres for MB still reached 70.06 % after six cycles.