脱氢
卡车
柴油
氢燃料
氢
能量载体
环境科学
氢技术
氢燃料车
废物管理
计算机科学
工艺工程
汽车工程
氢经济
催化作用
工程类
化学
生物化学
有机化学
作者
Sayandeep Biswas,Kariana Moreno Sader,William H. Green
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2023-08-09
卷期号:37 (22): 17003-17012
被引量:20
标识
DOI:10.1021/acs.energyfuels.3c01919
摘要
Decarbonization of long-haul trucks, which are the backbone of global supply chains, is necessary to meet climate goals. Currently, battery electric and conventional hydrogen powertrains are not cost-competitive solutions against diesel. Liquid Organic Hydrogen Carriers (LOHCs) are a promising fuel option that benefits from synergies with existing retail fuel distribution infrastructure, providing a cost-effective way to transport hydrogen energy. LOHCs are now used to deliver hydrogen gas to refueling stations, where it is then compressed and used to fuel trucks. However, this approach incurs ∼50% energy loss from the endothermic dehydrogenation and compression of hydrogen. We discuss an alternative concept based on onboard hydrogen release to address these pain points. We highlight recent advances in dehydrogenation reactor design, catalyst technologies, and hydrogen combustion engines that are relevant to the proposed system. Deficiencies in current technologies are discussed, along with potential research directions to address them. Initial analysis shows that the LOHC option, charged with blue hydrogen, achieves rough cost parity with diesel. The estimated well-to-wheel greenhouse gas emissions for this option are approximately one-third of diesel. Based on our analysis, LOHC-powered trucks featuring onboard dehydrogenation are a promising option to decarbonize long-haul trucking. However, making this option a reality will require dedicated study and development of core components for the power-dense, efficient, and robust onboard release of hydrogen from LOHCs along with efficient heat integration between the engine and the dehydrogenation reactor.
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