Sulfonic acid functionalized cellulose-derived (nano)materials: Synthesis and application

纤维素 生物高聚物 细菌纤维素 环境友好型 材料科学 纳米- 化学 磺酸 化学工程 纳米技术 有机化学 聚合物 复合材料 工程类 生态学 生物
作者
Mohaddeseh Sajjadi,Mahmoud Nasrollahzadeh,Mohammad Sattari,Hossein Ghafuri,Babak Jaleh
出处
期刊:Advances in Colloid and Interface Science [Elsevier BV]
卷期号:328: 103158-103158 被引量:13
标识
DOI:10.1016/j.cis.2024.103158
摘要

The preparation/application of heterogeneous (nano)materials from natural resources has currently become increasingly fascinating for researchers. Cellulose is the most abundant renewable polysaccharide on earth. The unique physicochemical, structural, biological, and environmental properties of this natural biopolymer have led to its increased application in many fields. The more desirable features of cellulose-based (nano)materials such as biodegradability, renewability, biocompatibility, cost-effectiveness, simplicity of preparation, environmentally friendly nature, and widespread range of applications have converted them into promising compounds in medicine, catalysis, biofuel cells, and water/wastewater treatment processes. Functionalized cellulose-based (nano)materials containing sulfonic acid groups may prove to be one of the most promising sustainable bio(nano)materials of modern times in the field of cellulose science and (nano)technology owing to their intrinsic features, high crystallinity, high specific surface area, abundance, reactivity, and recyclability. In this review, the developments in the application of sulfonated cellulose-based (nano)materials containing sulfonic acid (-SO3H) groups in catalysis, water purification, biological/biomedical, environmental, and fuel cell applications have been reported. This review provides an overview of the methods used to chemically modify cellulose and/or cellulose derivatives in different forms, including nanocrystals, hydrogels, films/membranes, and (nano)composites/blends by introducing sulfonate groups on the cellulose backbone, focusing on diverse sulfonating agents utilized and substitution regioselectivity, and highlights their potential applications in different industries for the generation of alternative energies and products.
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