析氧
过电位
催化作用
拉曼光谱
材料科学
电解水
分解水
过渡金属
纳米棒
氧气
氢氧化物
电化学
非阻塞I/O
化学工程
无机化学
纳米技术
化学
电解
物理化学
光催化
电极
生物化学
有机化学
工程类
物理
光学
电解质
作者
Jingjing Zhu,Jinmei Qian,Xuebing Peng,Baori Xia,Daqiang Gao
标识
DOI:10.1007/s40820-022-01011-3
摘要
Rational reconstruction of oxygen evolution reaction (OER) pre-catalysts and performance index of OER catalysts are crucial but still challenging for universal water electrolysis. Herein, we develop a double-cation etching strategy to tailor the electronic structure of NiMoO4, where the prepared NiMoO4 nanorods etched by H2O2 reconstruct their surface with abundant cation deficiencies and lattice distortion. Calculation results reveal that the double cation deficiencies can make the upshift of d-band center for Ni atoms and the active sites with better oxygen adsorption capacity. As a result, the optimized sample (NMO-30M) possesses an overpotential of 260 mV at 10 mA cm-2 and excellent long-term durability of 162 h. Importantly, in situ Raman test reveals the rapid formation of high-oxidation-state transition metal hydroxide species, which can further help to improve the catalytic activity of NiMoO4 in OER. This work highlights the influence of surface remodification and shed some light on activating catalysts.
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