The Emergence of High‐Performance Conjugated Polymer/Inorganic Semiconductor Hybrid Photoelectrodes for Solar‐Driven Photoelectrochemical Water Splitting

Solar-driven photoelectrochemical (PEC) energy conversion holds great potential in converting solar energy into storable and transportable chemicals or fuels, providing a viable route toward a carbon-neutral society. Conjugated polymers are rapidly emerging as a new class of materials for PEC water splitting. They exhibit many intriguing properties including tunable electronic structures through molecular engineering, excellent light harvesting capability with high absorption coefficients, and facile fabrication of large-area thin films via solution processing. Recent advances have indicated that integrating rationally designed conjugated polymers with inorganic semiconductors is a promising strategy for fabricating efficient and stable hybrid photoelectrodes for high-efficiency PEC water splitting. This review introduces the history of developing conjugated polymers for PEC water splitting. Notable examples of utilizing conjugated polymers to broaden the light absorption range, improve stability, and enhance the charge separation efficiency of hybrid photoelectrodes are highlighted. Furthermore, key challenges and future research opportunities for further improvements are also presented. This review provides an up-to-date overview of fabricating stable and high-efficiency PEC devices by integrating conjugated polymers with state-of-the-art semiconductors and would have significant implications for the broad solar-to-chemical energy conversion research.