析氧
X射线光电子能谱
电子转移
电催化剂
咪唑酯
分解水
材料科学
价(化学)
化学工程
催化作用
化学
光化学
无机化学
电化学
物理化学
电极
生物化学
光催化
有机化学
工程类
作者
Xiàn Yáng,Jun Cheng,Yang Xu,Hao Li,Weifeng Tu,Junhu Zhou
标识
DOI:10.1016/j.cej.2023.145076
摘要
Developing cost efficient, robust, non-precious metal electrocatalysts for oxygen evolution reaction (OER) is a significant challenge in water splitting for renewable energy conversion. A novel electrocatalyst of heterogeneous ultra-thin FeCo-LDH@Co(OH)2 nanosheets derived from 2D Zeolitic imidazolate framework facilitated electrons transfer for OER. DFT calculation revealed that heterogeneous interfaces reduced adsorption energy barriers of intermediates in rate-determining step of OER. The CoOOH with higher CoIII valence state derived from surface reconstruction, which was detected via in-situ Raman spectroscopy, activated O ions to provide higher intrinsic activity. XPS results confirmed that electrons transfer from Co(OH)2 to FeCo-LDH accelerated alkaline OER kinetics. The FeCo-LDH@Co(OH)2–0.5 exhibited low overpotentials of 230 mV at 10 mA cm−2 and maintained long durability for 300 h. This study opened up a new method for design and synthesis of ultrathin LDHs electrocatalysts.
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