材料科学
离子液体
溴化物
离子键合
离子电导率
咪唑
锌
阳极
溶解
金属
离子
无机化学
化学工程
有机化学
物理化学
催化作用
化学
电解质
电极
冶金
工程类
作者
Jiaqi Ke,Zhipeng Wen,Yang Yang,Rong Tang,Yongchao Tang,Minghui Ye,Xiaoqing Liu,Yufei Zhang,Cheng Chao Li
标识
DOI:10.1002/adfm.202301129
摘要
Abstract Artificial interface layer engineering is an efficacious modification strategy for protecting zinc anode from dendrite growth and byproducts formation. However, the high bulk ionic conductivity of most artificial interfacial layers is mainly contributed by the movement of anions (SO 4 2− ), which is the source of parasitic reactions on zinc anode. Herein, a high zinc ion donor transition (σZn 2+ = 3.89 × 10 −2 S cm −1 ) imidazole polymeric ionic liquid interface layer (1‐carboxymethyl‐3‐vinylimidazolium bromide monomer, CVBr) for Zn metal protection is designed. The N + atom of imidazole rings is connected by chains to form the cavities and the anions are confined within these cavities. Thus, the hindering effect of surrounding units on the anions leads to the subdiffusive regime, which inhibits the diffusion of SO 4 2− in interface and increases Zn 2+ transference number. Besides, the polycation‐anion coordination mechanism of PolyCVBr ensures accelerated Zn 2+ transition and realizes rapid internal Zn 2+ migration channel. As a result, the Zn@CVBr||AM symmetry cells deliver high bulk ionic conductivity (4.42 × 10 −2 S cm −1 ) and high Zn 2+ transference number (tZn 2+ = 0.88) simultaneously. The Zn@CVBr||AM‐NaV 3 O 8 pouch cells display the capacity retention of 88.9% after 190 cycles under 90° bending, verifying their potential practical application.
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