Advances in Selective Electrocatalytic Hydrogenation of Alkynes to Alkenes

Abstract Selective electrochemical hydrogenation of alkynes to alkenes under ambient conditions is a promising alternative to the traditional energy‐intensive and high‐cost thermocatalytic hydrogenation. However, the systematic summary on the electrocatalysts and electrolyzers remains lacked. Herein, we demonstrate a comprehensive review about recent achievements in the electrocatalysts including noble metal and non‐noble‐metal materials. Several effective strategies of catalyst design were developed to improve alkyne conversion, and alkene selectivity, for example, accelerating the formation of active hydrogen species, enhancing alkyne adsorption and suppressing the side reactions. Furthermore, the advantages and disadvantages of various electrolyzers are systematically discussed. Accordingly, major challenges and future trends in this field are proposed.