微生物燃料电池
燃料电池
氧气
氧还原反应
氧还原
还原(数学)
化学工程
多孔性
化学
钯
材料科学
废物管理
环境科学
催化作用
工程类
电化学
有机化学
物理化学
几何学
数学
电极
阳极
作者
Wenyi Wang,Long Tang,Chuanfu Cheng,Xueqin Wang,Yuanyuan Wang,Wencong Sun
标识
DOI:10.1016/j.jpowsour.2024.234143
摘要
Efficient and stable electrocatalysts with low platinum content are crucial for the practical application of fuel cells. The development of Pt-based single atom catalysts (SACs) has emerged as a promising research direction. In this study, we design and prepare a SACs based on MoS2 with Pt–S–Mo and Pd–S–Mo active sites (Pd, Pt–MoS2) by successively occupying vacancies, while maintaining the individual characteristics of the active sites. The resulting Pd, Pt–MoS2 catalyst exhibits excellent electrocatalytic activity for oxygen reduction reaction (ORR), long-term stability, and resistance to common poisons (SCN−, S2−, and methanol) under neutral conditions. Meanwhile, the microbial fuel cell (MFC) equipped with Pd, Pt–MoS2 exhibits excellent performance in terms of actual electricity generation performance and sewage purification capacity with an ultrahigh power density, average chemical oxygen demand (COD) removal rate, and coulombic efficiency (CE) of 1398.6 ± 43.5 mW m−2, 96.2 ± 2.2 %, and 22.5 ± 0.5 %, respectively. This strategy will provide new insights into the development of advanced bimetallic as well as polymetallic doped vacancies of MoS2 SACs.
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