环氧乙烷
电解质
离子
氧化物
高分子化学
乙醚
聚合物
聚乙烯
材料科学
酰亚胺
化学
乙烯
共聚物
有机化学
电极
物理化学
催化作用
作者
Heng Zhang,Fangfang Chen,Oier Lakuntza,Uxue Oteo,Lixin Qiao,Maria Martínez‐Ibáñez,Haijin Zhu,Javier Carrasco,Maria Forsyth,Michel Armand
标识
DOI:10.1002/anie.201908784
摘要
Trapping negative charges in polymer electrolytes using a frog-shaped, ether-functionalized anion (EFA) is presented by H. Zhang, J. Carrasco, M. Armand, and co-workers in their Communication on page 12070 ff. The bis(trifluoromethanesulfonyl)imide anion (TFSI), shown as a slippery tadpole, is highly mobile in poly(ethylene oxide) (PEO) matrix. In contrast, the ethylene oxide legs in EFA endow trapping interactions between the anion and PEO, which suppresses mobility (Artwork: Scixel, J. Carrasco, H. Zhang, M. Armand).
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