超级电容器
阳极
材料科学
非阻塞I/O
石墨烯
阴极
纳米晶
纳米技术
电极
电池(电)
氧化物
化学工程
储能
功率密度
电容
化学
催化作用
冶金
生物化学
功率(物理)
物理
物理化学
量子力学
工程类
作者
Minqian Mao,Li Cui,Kai Yang,Tong Xue,Jiae An,Man Yao,Jingtan Ma,Youjun Lu,Xianzhong Sun
标识
DOI:10.1016/j.est.2023.109226
摘要
Development of high-performance hybrid supercapacitors (HSCs) requires an excellent battery-type electrode material with highly active and stable nanostructures. In this report, we present a novel battery-type electrode material for HSCs which is built upon Ni2P/ZnP2 nanocrystals/ reduced graphene oxide (rGO) decorated on three-dimensional (3D) NiO/ZnO nanoflakes (NFs) by utilizing carbon cloth (CC) as current collector. This strategy is aimed to achieve a stable architecture, enhanced conductivity and accessibility of redox active sites, all of these can facilitate the transportation of ion/electron for faradaic reactions. Employing NiO/ZnO@Ni2P/ZnP2/rGO as the cathode which presents a remarkable mass specific capacity of 838.5 C g−1 and an outstanding cyclic lifespan (97.3 % charge retentions subsequent to 4000 cycles). In addition, a flexible HSC equipped with activated carbon (AC) as the anode as well represents a satisfactory energy density of 16.43 Wh kg−1 with a power density of 932.74 W kg−1 and an exceptional cycling stability (capacity retention of 91 % after 10,000 cycles).
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