阳极
材料科学
三相边界
催化作用
电极
氧化物
固体氧化物燃料电池
化学工程
分解
表征(材料科学)
多孔性
基本反应
纳米技术
无机化学
化学
复合材料
动力学
物理化学
冶金
有机化学
工程类
物理
量子力学
作者
Zerui Liu,Jixin Shi,Yuqing Wang,Yixiang Shi,Ningsheng Cai
出处
期刊:Meeting abstracts
日期:2023-08-28
卷期号:MA2023-01 (54): 342-342
标识
DOI:10.1149/ma2023-0154342mtgabs
摘要
Ammonia-fueled solid oxide fuel cells (SOFCs) have attracted the focus of researchers due to the feature of no carbon emission. Understanding the reaction mechanism is vital for the design and optimization of NH 3 -fed SOFCs. However, the catalytic decomposition reactions involved in porous electrodes led to the difficulty to distinguish the anode reaction mechanism. In the present study, we utilized a patterned anode to get a designed triple phase boundary (TPB) and avoid the effects of porous electrodes. In the performance test, we found that the current density of the NH 3 -fed SOFC was approximately 20% of that of the H 2 -fed SOFC under a similar working position at 750℃. The difference may mainly resulted from the limit of catalytic decomposition of NH 3 caused by the narrow reactive area in the patterned electrode. A one-dimensional elementary reaction model was further developed to validate this hypothesis and to provide additional evidence for the reaction mechanisms of the NH 3 -fed SOFC.
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