Synthesis of CeO2–BiVO4 nano photocatalyst material and used for the degradation of gaseous formaldehyde

光催化 甲醛 材料科学 光降解 扫描电子显微镜 漫反射红外傅里叶变换 钒酸铋 催化作用 可见光谱 化学工程 光致发光 光化学 核化学 化学 复合材料 有机化学 光电子学 工程类
作者
Chia-Chen Lu,Thamraa Alshahrani,Ren‐Jang Wu,Umesh Fegade,Ganesh Jethave,Amir Al‐Ahmed,Firoz Khan,Sachin Kolate
出处
期刊:Optical Materials [Elsevier]
卷期号:144: 114310-114310 被引量:7
标识
DOI:10.1016/j.optmat.2023.114310
摘要

Formaldehyde is one of the common volatile organic compound (VOC) found in indoor environment. Reducing indoor formaldehyde exposure levels is an important issue because toxicological studies have demonstrated its carcinogenicity. In this study, hydrothermal method was used to prepare ceria-bismuth vanadate (CeO2–BiVO4) composite photocatalyst. CeO2–BiVO4 has the advantages of high-efficiency photocatalytic activity, and high stability making it a promising photocatalytic material in the fields of energy conversion and environmental protection. As-prepared samples were characterized by X-ray diffraction (XRD), reflection ultraviolet–visible spectroscopy (UV–Vis), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). XRD, TEM, and SEM verified that the material was successfully prepared. The energy level was measured by UV–Vis, and it was verified by PL that the CeO2–BiVO4 can reduce the recombination rate of electron holes. Here, BiVO4 is added to reduce the band gap of CeO2 to produce a visible light-driven catalyst. The photodegradation reaction of formaldehyde is carried out by mixing in different proportions of BiVO4 in to CeO2. The light source used in this experiment is a green light. In the experiment of formaldehyde degradation by irradiating CeO2/BiVO4 with a green light, the concentration of product carbon dioxide (CO2) and water (H2O) increases with the irradiation time. The experimental results show that CeO2-BiVO4 (4:1) catalyst has the highest formaldehyde degradation rate of 78%, and the total reaction time is 240 min. The importance of CeO2–BiVO4 as a photocatalytic material in formaldehyde degradation is to provide an environmentally friendly and efficient method to purify indoor air. It can help reduce the potential harm of formaldehyde to human health, improve indoor air quality, and contribute to creating a healthier and more comfortable indoor environment.
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