Highly Efficient White Emission from Semiconductor Ink Based on Copper Iodide Nanoclusters

Recent developments in the perovskite field have aimed at exploring cluster-based organic-inorganic copper(I) halides as novel luminescent materials because of their low toxicity and structural diversity. However, the poor framework stability and low dispersion in solvent constitute the key challenges to their practical applications such as luminescent inks. Herein, we report the preparation of highly luminescent inks via one-pot solution synthesis, which consisted of ionic CumIn clusters (tetrabutylammonium copper iodide) coupled with polymer polyvinylpyrrolidone (PVP). Benefiting from the high-affinity PVP to stabilize and disperse the Cu-I inorganic units, the obtained hybrid nanocrystals exhibit high structural stabilitiy/photostability and good dispersion in ethanol. The characteristics of bright white light emission from inks were explored by temperature-dependent photoluminescence experiments and theoretical calculations. Attractively, the stable, highly luminescent inks show great potential for practical applications, such as anticounterfeiting and imaging identification. Our study offers a new material designing strategy that may be generalized to many other material classes.