Ultrasensitive ammonia gas sensor based on Ti3C2Tx/Ti3AlC2 planar composite at room temperature

Two-dimensional (2D) transition metal carbides (MXene) have attracted great attention for device applications due to their unique structures and excellent properties, such as high electrical conductivity and abundant functional groups on the surface. However, gas sensors based on Ti3C2Tx MXene have the problems of high detection limit and poor long-term stability. Herein, we report a simple method to prepare Ti3C2Tx/Ti3AlC2 planar composite gas sensing materials using high molar ratio of HCl and LiF with Ti3AlC2 as a framework. The Ti3C2Tx/Ti3AlC2 planar composite gas sensor has a high sensitivity, good selectivity and low detection limit for NH3, which can detect 50 ppb (1.2%) at room temperature ((25 ± 2) ℃). Furthermore, the gas sensor has good repeatability and long-term stability. After 120 days, the response of the gas sensor to 500 ppb of NH3 fluctuated little due to the Ti3AlC2 as a framework. The superior performances can be attributed to the special heterojunction between Ti3C2Tx and Ti3AlC2 and the high proportion of -O and -OH functional groups on the surface of Ti3C2Tx/Ti3AlC2 composite. This study provides an important reference for the realization of high performance NH3 sensing by Ti3C2Tx.