化学
吸附
废水
氯化物
污染物
离子键合
阳离子聚合
自来水
共价有机骨架
化学工程
共价键
有机化学
环境科学
环境工程
离子
工程类
作者
Sohom Chandra,Atikur Hassan,Prince,Akhtar Alam,Neeladri Das
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2022-08-20
卷期号:4 (9): 6630-6641
被引量:11
标识
DOI:10.1021/acsapm.2c00989
摘要
The use of ionic porous materials for the detoxification of water has been receiving widespread research attention since the last decade. Such materials are associated with attractive features such as a facile synthetic route, easy scalability, and excellent performance in the removal of pollutants from wastewater. To further enrich the literature on ionic porous materials as superior adsorbents, this work describes the construction of an ionic covalent organic network (iCON-5) using Schiff-base polycondensation of triamminoguanidium chloride and 4,4′,4″-((1,3,5-triazine-2,4,6-triyl)tris(oxy))tribenzaldehyde. The resulting polymeric framework exhibits good physicochemical stability. The presence of exchangeable chloride counteranions in the polymeric network ensures the efficient capture of various anionic pollutants from wastewater. The iCON-5 displays a good uptake capacity toward a wide range of inorganic/organic species (CrO42–, TcO4–, I3–, diclofenac, and picrate) that are proclaimed water pollutants. In addition, iCON-5 is easy to regenerate and can be reused at least 5 times without significant compromise in uptake capacities. Furthermore, the cationic network is competent in the extraction of anionic pollutants from systems mimicking real-world samples (such as pollutant-spiked tap water, seawater, river water, lake water, and pond water). Thus, iCON-5 has the desired characteristics anticipated in a porous adsorbent for the sequestration of various anionic contaminants from wastewater.
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